Issue 15, 1991
From the journal:

Journal of the Chemical Society, Chemical Communications

The mechanism of methyl radical loss from CH3CH[double bond, length half m-dash]CHCH(CH3)OCH3+˙ and CH2[double bond, length half m-dash]C(CH3)CH(CH3)OCH3+˙: a not-so-simple cleavage

Richard D. Bowen  and  Andrew D. Wright  

Abstract

Loss of a methyl radical from CH3CH[double bond, length half m-dash]CHCH(CH3)OCH3+˙ and CH2[double bond, length half m-dash]C(CH3)CH(CH3)OCH3+˙ is shown by 2H-labelling and collision-induced dissociation experiments to involve elimination of the methyl group originally attached to the double bond, with formation of CH2[double bond, length half m-dash]CHC(CH3)[double bond, length half m-dash]O+CH3 as the fragment ion.

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Article information

DOI
https://doi.org/10.1039/C39910001055
Article type
Paper

J. Chem. Soc., Chem. Commun., 1991, 1055-1057

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The mechanism of methyl radical loss from CH3CH[double bond, length half m-dash]CHCH(CH3)OCH3+˙ and CH2[double bond, length half m-dash]C(CH3)CH(CH3)OCH3+˙: a not-so-simple cleavage

R. D. Bowen and A. D. Wright, J. Chem. Soc., Chem. Commun., 1991, 1055 DOI: 10.1039/C39910001055

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