The natural cyclic peroxide G3 is rearranged in the presence of a RuII–tertiary phosphine complex, to an ene pentadione and to a bicyclic hemiacetal butenolide; the structures have been respectively assigned by CPG–MS analysis and X-ray studies.
M. Baltas, M. Benbakkar and L. Gorrichon, J. Chem. Soc., Chem. Commun., 1991, 1044 DOI: 10.1039/C39910001044
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