The successive reaction of diallyl amines 1 with several alkyllithium reagents and dichlorodimethylsilane or dichlorodiethylgermanium leads, after hydrolysis, to the corresponding azasilocine and azagermocine derivatives 3 and 4.
J. Barluenga, F. Foubelo, R. González, F. J. Fañanás and M. Yus, J. Chem. Soc., Chem. Commun., 1991, 1001 DOI: 10.1039/C39910001001
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