The protonation of the VII bridging dinitrogen complex [{V(C6H4CH2NMe2)2(C5H5N)}2N2] yields 2/3NH3, 2/3N2 and unidentified VIII-containing products, although hydrazine might have been expected on the basis of its structure; another factor influencing the product of dinitrogen protonation appears to be the availability of electrons from the metal atoms.
G. J. Leigh, R. Prieto-Alcón and J. R. Sanders, J. Chem. Soc., Chem. Commun., 1991, 921 DOI: 10.1039/C39910000921
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