Issue 14, 1991
From the journal:

Journal of the Chemical Society, Chemical Communications

Benzoyl–carbene coupling by [CpM(COPh)(CO)2{[double bond, length half m-dash]C(CH2)3NMe}](M = Mo, W)

Harry Adams,   Neil A. Bailey,   Carin E. Tattershall  and  Mark J. Winter  

Abstract

Treatment of the anions [CpM{[double bond, length half m-dash][graphic omitted]Me}(CO)2](M = Mo or W) with PhC([double bond, length half m-dash]O)Cl results in the corresponding η1-benzoyls [CpM(η1-COPh){[double bond, length half m-dash][graphic omitted]Me}(CO)2] which undergo benzoyl–carbene coupling, most likely through 1,2-migrations of benzoyl to carbene, in forming the complexes [Cp[graphic omitted]Me}(CO)2].

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Article information

DOI
https://doi.org/10.1039/C39910000912
Article type
Paper

J. Chem. Soc., Chem. Commun., 1991, 912-914

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Benzoyl–carbene coupling by [CpM(COPh)(CO)2{[double bond, length half m-dash]C(CH2)3NMe}](M = Mo, W)

H. Adams, N. A. Bailey, C. E. Tattershall and M. J. Winter, J. Chem. Soc., Chem. Commun., 1991, 912 DOI: 10.1039/C39910000912

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