Glucoside hydrolysis and chemoselective reduction of secologanin ethylene acetal 2 with baker's yeast affords a C-1 reduced aglucone 4 from which (+)-antirhine 8 is obtained in a four-step sequence.
R. T. Brown, B. E. N. Dauda and C. A. M. Santos, J. Chem. Soc., Chem. Commun., 1991, 825 DOI: 10.1039/C39910000825
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