A new enantiocontrolled synthesis of L-erythro- and D-threo-sphingosines has been established starting from (R,R)- and meso-1,2-divinylethylene glycols via the anomalous version of the Katsuki–Sharpless asymmetric epoxidation reaction as the key step.
S. Takano, Y. Iwabuchi and K. Ogasawara, J. Chem. Soc., Chem. Commun., 1991, 820 DOI: 10.1039/C39910000820
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