Issue 12, 1991

Formation of novel 1 : 2 adducts between Bun3P·CS2 and electron-deficient alkynes

Abstract

The zwitterionic adduct between tri-n-butylphosphine and carbon disulphide reacts under neutral conditions with two equivalents of dimethyl and diethyl acetylenedicarboxylate, dibenzoylacetylene and methyl benzoylpropiolate to give novel crystalline dithiole-containing ylides whose structure is established by X-ray crystallography.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1991, 812-814

Formation of novel 1 : 2 adducts between Bun3P·CS2 and electron-deficient alkynes

R. A. Aitken, G. Ferguson and S. V. Raut, J. Chem. Soc., Chem. Commun., 1991, 812 DOI: 10.1039/C39910000812

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