Reaction of tris(triethylphosphine)trimethylsilyldiazomethylrhodium(I) with isocyanides. Synthesis and X-ray structure of the first 1H-1,2,3-triazolato complex with a metal–carbon bond
Abstract
Two new C-bonded 1H-1,2,3-triazolato rhodium(I) compounds have been synthesized from the 1,3-dipolar cycloaddition of the diazo complex [Rh(PEt3)3{C(N2)SiMe3}] with isocyanides RNC (R = But and Bun).