Issue 12, 1991

Reaction of tris(triethylphosphine)trimethylsilyldiazomethylrhodium(I) with isocyanides. Synthesis and X-ray structure of the first 1H-1,2,3-triazolato complex with a metal–carbon bond

Abstract

Two new C-bonded 1H-1,2,3-triazolato rhodium(I) compounds have been synthesized from the 1,3-dipolar cycloaddition of the diazo complex [Rh(PEt3)3{C(N2)SiMe3}] with isocyanides RNC (R = But and Bun).

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1991, 809-810

Reaction of tris(triethylphosphine)trimethylsilyldiazomethylrhodium(I) with isocyanides. Synthesis and X-ray structure of the first 1H-1,2,3-triazolato complex with a metal–carbon bond

E. Deydier, M. Menu, M. Dartiguenave and Y. Dartiguenave, J. Chem. Soc., Chem. Commun., 1991, 809 DOI: 10.1039/C39910000809

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