Reaction of optically active nitroalkanes with allyl Grignard reagents affords E-Z mixtures of nitrones which can be reduced to chiral hydroxylamines and amines.
G. Bartoli, E. Marcantoni and M. Petrini, J. Chem. Soc., Chem. Commun., 1991, 793 DOI: 10.1039/C39910000793
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