Optically active trans-benzoperhydroindan 1 and its enantiomer have been synthesised by thermolysis of the optically active alkenic benzocyclobutene 10 as a key process.
H. Nemoto, N. Matsuhashi and K. Fukumoto, J. Chem. Soc., Chem. Commun., 1991, 705 DOI: 10.1039/C39910000705
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