Tungsten-η4-carboxylated-1,3-diene cations in both s-trans and s-cis forms have been prepared and the influence of the diene conformation on its nucleophilic regiochemistry is demonstrated; the synthetic utility of these diene complexes is reported, and the crystal structure of one product has been determined.
M. Cheng, Y. Ho, G. Lee, S. Peng and R. Liu, J. Chem. Soc., Chem. Commun., 1991, 697 DOI: 10.1039/C39910000697
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