XANES and EXAFS investigations of titanium silicalite-1, a microporous material with the structural features of zeolite ZSM-5, show that a large part of the titanium is coordinated octahedrally and probably occupies framework positions, a local environment that provides an explanation for the extraordinary caltalytic properties of this material.
P. Behrens, J. Felsche, S. Vetter, G. Schulz-Ekloff, N. I. Jaeger and W. Niemann, J. Chem. Soc., Chem. Commun., 1991, 678 DOI: 10.1039/C39910000678
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