1-Alkoxy and 1-acetoxy substituted tricarbonyl(η5-cyclohexadienyl)iron(1+) complexes undergo reactions with nucleophiles at opposite ends of the π-system in a reversal of regiocontrol that offers novel possibilities for complementary control strategies in applications in asymmetric synthesis, since the two series of complexes can be obtained from the same precursor.
G. R. Stephenson, P. W. Howard, D. A. Owen and A. J. Whitehead, J. Chem. Soc., Chem. Commun., 1991, 641 DOI: 10.1039/C39910000641
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