Free-radical-chain reduction of organic halides is accomplished with heptamethyltrisilanethiol, a reducing agent combining the good hydrogen donating ability of a thiol and the excellent halogen abstracting properties of a silyl radical.
J. Daroszewski, J. Lusztyk, M. Degueil, C. Navarro and B. Maillard, J. Chem. Soc., Chem. Commun., 1991, 586 DOI: 10.1039/C39910000586
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