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Issue 8, 1991
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Lewis acid complexed heteroatom carbanions; a new concept for α-metallation of tertiary amines

Abstract

BF3 complexes of typical benzylic, allylic and saturated N-methyl tertiary amines were α-lithiated, with lithium tetramethylpiperidide (LTMP) or sec-butyllithium, and were treated with electrophiles.

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Article type: Paper
DOI: 10.1039/C39910000568
Citation: J. Chem. Soc., Chem. Commun., 1991,0, 568-570
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    Lewis acid complexed heteroatom carbanions; a new concept for α-metallation of tertiary amines

    S. V. Kessar, P. Singh, R. Vohra, N. P. Kaur and K. N. Singh, J. Chem. Soc., Chem. Commun., 1991, 0, 568
    DOI: 10.1039/C39910000568

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