Issue 8, 1991
From the journal:

Journal of the Chemical Society, Chemical Communications

Synthesis and structure of a perpendicular bridging alkylidyneamine ligand in [W2(η-C5H4Pri)2Cl4(µ-Cl)(µ-EtCNH)]

Qian Feng,   Montserrat Ferrer,   Malcolm L. H. Green,   Patrick C. McGowan,   Philip Mountford  and  Victor S. B. Mtetwa  

Abstract

Treatment of the W[triple bond, length half m-dash]W triply-bonded dimers [W2(η-C5H4R)2Cl4](R = Pri or Me) with R′CN (R′= Me, Et, or Ph) followed by HCl gas affords the complexes [W2(η-C5H4R)2Cl4(µ-Cl)(µ-R′CNH)] in quantitative yield; the X-ray crystal structure for R = Pri, R′= Et reveals a perpendicular bridging EtCNH ligand.

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Article information

DOI
https://doi.org/10.1039/C39910000552
Article type
Paper

J. Chem. Soc., Chem. Commun., 1991, 552-554

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Synthesis and structure of a perpendicular bridging alkylidyneamine ligand in [W2(η-C5H4Pri)2Cl4(µ-Cl)(µ-EtCNH)]

Q. Feng, M. Ferrer, M. L. H. Green, P. C. McGowan, P. Mountford and V. S. B. Mtetwa, J. Chem. Soc., Chem. Commun., 1991, 552 DOI: 10.1039/C39910000552

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