As the first example of asymmetric hydrogenolysis of an epoxide, the homogeneous catalytic asymmetric hydrogenolysis of sodium epoxysuccinate was accomplished by using rhodium catalysts containing chiral phosphine ligands.
A. S. C. Chan and J. P. Coleman, J. Chem. Soc., Chem. Commun., 1991, 535 DOI: 10.1039/C39910000535
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