Metathesis copolymerisation of cycloalkenes with substituted acetylenes, typically norbornene with phenylacetylene, is achieved for the first time, which verifies that the polymerisation of substituted acetylenes by group 6 transition metal catalysts proceeds by the metal carbene mechanism.
T. Masuda, T. Yoshida, H. Makio, Mohd. Z. Ab. Rahman and T. Higashimura, J. Chem. Soc., Chem. Commun., 1991, 503 DOI: 10.1039/C39910000503
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