Issue 7, 1991

Synthesis and thermal reactions of perfluoroalkylsulphonyl substituted ylides

Abstract

The synthesis of several perfluoroalkylsulphonyl substituted ylides is described; thermal decomposition of the phenyliodonio(cyanononafluorobutylsulphonyl)methanide 3a in cyclohexene yields the bicyclo[4.1.0]heptane derivative, while the phenyliodoniobis(nonafluorobutylsulphonyl)methanide 3c gives an insertion reaction.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1991, 470-471

Synthesis and thermal reactions of perfluoroalkylsulphonyl substituted ylides

J. Hackenberg and M. Hanack, J. Chem. Soc., Chem. Commun., 1991, 470 DOI: 10.1039/C39910000470

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