The photoelectron spectrum of Chlorophosphaethyne, generated in the gas phase by dehydrochlorination of trichloromethylphosphine on a solid base, is reported; the spectrum is quite consistent with the spectra of the related cyanogen halides or haloacetylenes and indicates a large interaction between the degenerate P![[triple bond, length half m-dash]](https://www.rsc.org/images/entities/char_e007.gif)
C triple bond and the chlorine lone pair.
S. Lacombe, G. Pfister-Guillouzo, J. C. Guillemin and J. M. Denis, J. Chem. Soc., Chem. Commun., 1991, 403 DOI: 10.1039/C39910000403
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