The new cluster cation [Co4Cu3(CO)8(Me2PCH2PMe2)4]+ contains a central copper atom bridging two Co2Cu triangles; on the basis of, (i) its approximately square-planar stereochemistry, and (ii) electron counting considerations, it is suggested that the central copper atom has the d8 CuIII electron configuration, which is unique in copper clusters.
H. A. Mirza, J. J. Vittal and R. J. Puddephatt, J. Chem. Soc., Chem. Commun., 1991, 309 DOI: 10.1039/C39910000309
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