Triphenylsilanol is a selective host for ethanol in the presence of other simple homologous alcohols and forms a 4 : 1 coordinatoclathrate stabilised by hydrogen bonds; thermal decomposition takes place in a two-step process with the formation of a new intermediate phase.
S. A. Bourne, L. R. Nassimbeni, K. Skobridis and E. Weber, J. Chem. Soc., Chem. Commun., 1991, 282 DOI: 10.1039/C39910000282
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