Two new members of the heterometallic trinuclear incomplete cubane-like cluster family, with the core [M2AgS4]3+(M = Mo, W), were synthesized and characterised; the Mo–Mo [W–W] bond was found to be 2.881(4)[2.874(1)]Å and two Mo–Ag [W–Ag] non-bonding distances 3.010(4) and 3.117(4)[3.112(2), 3.055(2)]Å.
Z. Nianyong, W. Xintao and L. Jiaxi, J. Chem. Soc., Chem. Commun., 1991, 235 DOI: 10.1039/C39910000235
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