Issue 4, 1991

Reductive carbonylation of alkenes using zwitterionic rhodium complexes as catalysts

Abstract

Alkenes react with carbon monoxide, sodium borohydride, propan-2-ol and a catalytic amount of Rh(cod)(η6-PhBPh3)(cod = cyclooctadiene) to give alcohols in fine yields; high regioselectivity for the branched or linear alcohol is usually observed, depending on the organic substrate.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1991, 233-234

Reductive carbonylation of alkenes using zwitterionic rhodium complexes as catalysts

J. Zhou and H. Alper, J. Chem. Soc., Chem. Commun., 1991, 233 DOI: 10.1039/C39910000233

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