Issue 4, 1991

Use of molecular sieves for promotion of diastereoselectivity in palladium-catalysed oxidative cyclisation. Reversal of diastereofacial selectivity

Abstract

Molecular sieves have a decisive influence on the oxidative cyclisation of cis-1,2-divinylcyclohexane, resulting in enhanced diastereoselectivity (17–62%) as well as, occasionally, in opposite absolute configuration of the newly created chiral centres.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1991, 218-220

Use of molecular sieves for promotion of diastereoselectivity in palladium-catalysed oxidative cyclisation. Reversal of diastereofacial selectivity

A. Heumann, L. Tottie and C. Moberg, J. Chem. Soc., Chem. Commun., 1991, 218 DOI: 10.1039/C39910000218

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