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Issue 2, 1991
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Reactions of 1,3-epithionaphtho[1,8-cd][1,2λ5,6λ5]thiadiphosphinine-1,3-dithione; the preparation and X-ray structure of NpP(S)(SMe)SP(S)(OMe), the first C3P2S ring

Abstract

NpP2S41(Np = C10H6, naphthalene-1,8-diyl) reacts with carbonyl groups to give thiocarbonyls whilst refluxing 1 in methanol results in cleavage of one of the P–S–P bridges and formation of the new heterocycle 3 which contains a C3P2S ring with the phosphorus atoms asymmetrically substituted by methoxy and thiomethoxy groups.

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Article type: Paper
DOI: 10.1039/C39910000116
Citation: J. Chem. Soc., Chem. Commun., 1991,0, 116-117
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    Reactions of 1,3-epithionaphtho[1,8-cd][1,2λ5,6λ5]thiadiphosphinine-1,3-dithione; the preparation and X-ray structure of NpP(S)(SMe)SP(S)(OMe), the first C3P2S ring

    M. Eleftheriou, J. Novosad, D. J. Williams and J. D. Woollins, J. Chem. Soc., Chem. Commun., 1991, 0, 116
    DOI: 10.1039/C39910000116

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