Issue 2, 1991

Formation, characterization and reactivity of a selenaza dication [R2Se+–N+R3] from N-methyl-5H,7H-dibenzo[b,g][1,5]selenazocine

Abstract

A new heterocycle containing selenium and nitrogen atoms, N-methyl-5H,7H-dibenzo[b,g][1,5]selenazocine 1, has been synthesized; the reaction of the selenoxide of 1 with (CF3SO2)2O gave a novel selenaza dication salt which was characterized by 77Se NMR spectroscopy, and the dication acts as an oxidizing agent.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1991, 98-99

Formation, characterization and reactivity of a selenaza dication [R2Se+–N+R3] from N-methyl-5H,7H-dibenzo[b,g][1,5]selenazocine

H. Fujihara, H. Mima, T. Erata and N. Furukawa, J. Chem. Soc., Chem. Commun., 1991, 98 DOI: 10.1039/C39910000098

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