Ketones and aryl or vinyl halides couple to give divinyl or arylvinyl amines in the presence of the titanium isocyanate complex [3THF·Mg2Cl2O·TiNCO]1 and a palladium catalyst, via transmetallation of the titano imine complex 6 with aryl or vinyl palladium bromide (THF tetrahydrofuran).
Y. Uozumi, M. Mori and M. Shibasaki, J. Chem. Soc., Chem. Commun., 1991, 81 DOI: 10.1039/C39910000081
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