Generation and spectroscopic characterization of the first chloro(2,4,6-tri-t-butylphenylimino)phosphine complexes
Abstract
Reactions of X–PNAr (Ar = 2,4,6-But3C6H2; X = halogen), with a variety of nickel(0) and platinum(II) phosphine complexes afford the first examples of σ-complexes containing P-functionalized iminophosphines whose structures have been elucidated by NMR spectroscopy.