Issue 1, 1991

Manganese carbonyl and phase transfer catalysed, stereospecific hydroacylation of allenes to α,β-unsaturated ketones

Abstract

Phase transfer (5 mmol dm–3 NaOH, CH2Cl2, cetyltrimethylammonium bromide) catalysed reaction of allenes with carbon monoxide, decacarbonyldimanganese and methyl iodide affords α,β-unsaturated ketones in a stereospecific process.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1991, 8-9

Manganese carbonyl and phase transfer catalysed, stereospecific hydroacylation of allenes to α,β-unsaturated ketones

N. Satyanarayana and H. Alper, J. Chem. Soc., Chem. Commun., 1991, 8 DOI: 10.1039/C39910000008

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