Glucopyranosides of methyl-1,2,6-thiadiazin-3(2H)-one 1,1-dioxides have been synthesized and their rotational isomerism studied. Two of them exist, in solution, as mixtures of syn : anti rotamers, at room temperature. In the case of the diglucoside, the barriers to rotation about both glycosidic bonds have been calculated by dynamic 13C NMR.
P. Goya, A. Martinez and M. L. Jimeno, J. Chem. Soc., Perkin Trans. 2, 1990, 783 DOI: 10.1039/P29900000783
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