SCHEDULED MAINTENANCE
The kinetic data obtained in the study of the title reaction reveal unusual substituent effects. A logarithmic plot of reactivity data versus substituent constants (σ and/or σ–) shows a ‘zigzag’ trend; it is suggested that this depends on a changeover of the mechanism and/or of the rate-determining step.
V. Frenna, S. Buscemi, D. Spinelli and G. Consiglio, J. Chem. Soc., Perkin Trans. 2, 1990, 215 DOI: 10.1039/P29900000215
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