Nucleophilic ring opening of chiral epoxy diols, derived from L-ascorbic acid, with 2-lithio-1,3-dithianes allowed preparation of long-chain (R)- and (S)-α-hydroxy acids of high optical purity.
K. Yamagata, Y. Yamagiwa and T. Kamikawa, J. Chem. Soc., Perkin Trans. 1, 1990, 3355 DOI: 10.1039/P19900003355
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