Asymmetric reduction of N-substituted ketimines with the reagent prepared from borane and (S)-(–)-2-amino-3-methyl-1,1-diphenylbutan-1-ol (itsuno's reagent): enantioselective synthesis of optically active secondary amines

Byung Tae Cho; Yu Sung Chun

doi:10.1039/P19900003200

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Asymmetric reduction of N-substituted ketimines with the reagent prepared from borane and (S)-(–)-2-amino-3-methyl-1,1-diphenylbutan-1-ol (itsuno's reagent): enantioselective synthesis of optically active secondary amines

Byung Tae Cho and Yu Sung Chun

Abstract

Itsuno's Reagent (1) reduced N-substituted ketimines in very high yields to the corresponding amines with high optical induction.

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DOI: https://doi.org/10.1039/P19900003200
Article type: Paper

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J. Chem. Soc., Perkin Trans. 1, 1990, 3200-3201

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Asymmetric reduction of N-substituted ketimines with the reagent prepared from borane and (S)-(–)-2-amino-3-methyl-1,1-diphenylbutan-1-ol (itsuno's reagent): enantioselective synthesis of optically active secondary amines

B. T. Cho and Y. S. Chun, J. Chem. Soc., Perkin Trans. 1, 1990, 3200 DOI: 10.1039/P19900003200

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Journal of the Chemical Society, Perkin Transactions 1

Asymmetric reduction of N-substituted ketimines with the reagent prepared from borane and (S)-(–)-2-amino-3-methyl-1,1-diphenylbutan-1-ol (itsuno's reagent): enantioselective synthesis of optically active secondary amines

Abstract

Article information

Download Citation

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Asymmetric reduction of N-substituted ketimines with the reagent prepared from borane and (S)-(–)-2-amino-3-methyl-1,1-diphenylbutan-1-ol (itsuno's reagent): enantioselective synthesis of optically active secondary amines

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