Issue 11, 1990

The photochemical behaviour of 2-methylcyclohept-2-enones

Abstract

An efficient dimerisation of 1,3-dimethyl-8-oxabicyclo[5.3.0]dec-3-ene-2,9-dione 4 has been discovered, and probably involves an initial photo-induced formation of the transcyclohept-2-enone which then undergoes thermal dimerisation. Irradiation of the complex cycloheptenone, 1,3,10-trimethyl-8-oxabicyclo[5.3.0]dec-3-ene-2,9-dione 1 provided an 85% yield of a novel tricycle (and no dimer), tentatively identified as 1,8,10-trimethyl-3-oxatricyclo[6.2.0.04,10]decane-2,9-dione.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1990, 3081-3083

The photochemical behaviour of 2-methylcyclohept-2-enones

L. C. de Almeida Barbosa, J. Mann and W. J. Cummins, J. Chem. Soc., Perkin Trans. 1, 1990, 3081 DOI: 10.1039/P19900003081

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