Enantioselective synthesis of (–)-malyngolide (1) was accomplished by employing diastereo-selective addition of nonylmagnesium bromide to the 2-acylfuran derivative (4), followed by a ring transformation of the resulting optically active 2-furylalcohol (5) to give the pyranone derivative (7) as key steps.
T. Honda, M. Imai, K. Keino and M. Tsubuki, J. Chem. Soc., Perkin Trans. 1, 1990, 2677 DOI: 10.1039/P19900002677
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