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The reductive ring-contraction of the sulphonate ester of 7α,18-dihydroxykaurenolide with lithium aluminium hydride is shown to afford the 6-epi-7,19-dihydroxygibberell-16-ene.
M. Alam and J. R. Hanson, J. Chem. Soc., Perkin Trans. 1, 1990, 2577 DOI: 10.1039/P19900002577
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