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Issue 8, 1990
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Synthesis based on cyclohexadienes: Part 4. Novel synthesis of the 6-aryl-2,4-dimethoxybenzoates. Alternariol and methyl trimethylaltenusin

Abstract

A novel method for the preparation of 6-aryl-2,4-dimethoxybenzoic acids involving the Alder–Rickert reaction of 1,5-dimethoxycyclohexa-1,4-dienes and arylpropiolic esters is described. This strategy has been extended to the synthesis of the mould metabolite alternariol and methyl trimethylaltenusin.

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Article type: Paper
DOI: 10.1039/P19900002233
J. Chem. Soc., Perkin Trans. 1, 1990, 2233-2237

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    Synthesis based on cyclohexadienes: Part 4. Novel synthesis of the 6-aryl-2,4-dimethoxybenzoates. Alternariol and methyl trimethylaltenusin

    C. C. Kanakam, N. S. Mani and G. S. R. S. Rao, J. Chem. Soc., Perkin Trans. 1, 1990, 2233
    DOI: 10.1039/P19900002233

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