The eudesmane precursor (6) containing a trans ring fusion has been prepared stereoselectively by an inverse electron-demand, intramolecular (4 + 2)π cycloaddition with phenylsulphonyl as controlling group.
A. Weichert and H. M. R. Hoffmann, J. Chem. Soc., Perkin Trans. 1, 1990, 2154 DOI: 10.1039/P19900002154
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