A number of interconversions of compounds of the bicyclo[4.2.1]nonane-7-spiro-2′-(tetrahydrofuran) ring system, comprising reduction, oxidation, and Grignard reactions, confirm the structural and conformational stability of this carbon skeleton. Representative compounds undergo scission under electron impact according to a common fragmentation pattern.
F. Kurzer and A. A. Allen, J. Chem. Soc., Perkin Trans. 1, 1990, 2019 DOI: 10.1039/P19900002019
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