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Issue 4, 1990
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Perkin communications. Radical cyclization in stereospecific introduction of chirality at ‘off template site’ of 1,2-O-isopropylidene-α-D-xylo-hexofuranose

Abstract

Bromoacetals derived from 5,6-dideoxy-1,2-O-isopropylidene-α-D-xylo-hex-5-ynofuranose (9) undergo facile free radical cyclization leading to the formation of olefinic acetals which are chemially manipulated to introduce either of the chiralities at C-5 of α-D-hexofuranose.

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Article information


J. Chem. Soc., Perkin Trans. 1, 1990, 1211-1213
Article type
Paper

Perkin communications. Radical cyclization in stereospecific introduction of chirality at ‘off template site’ of 1,2-O-isopropylidene-α-D-xylo-hexofuranose

A. V. R. Rao, J. S. Yadav, C. S. Rao and S. Chandrasekhar, J. Chem. Soc., Perkin Trans. 1, 1990, 1211
DOI: 10.1039/P19900001211

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