SCHEDULED MAINTENANCE
Bromoacetals derived from 5,6-dideoxy-1,2-O-isopropylidene-α-D-xylo-hex-5-ynofuranose (9) undergo facile free radical cyclization leading to the formation of olefinic acetals which are chemially manipulated to introduce either of the chiralities at C-5 of α-D-hexofuranose.
A. V. R. Rao, J. S. Yadav, C. S. Rao and S. Chandrasekhar, J. Chem. Soc., Perkin Trans. 1, 1990, 1211 DOI: 10.1039/P19900001211
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