Issue 4, 1990

Photochemistry of halogenocarbon compounds. Part 5. Photolysis of fluorinated 1,2,3-triazine derivatives

Abstract

Photolysis experiments are described on perfluoro-1,2,3-triazine (9) and its corresponding perfluoro-isopropyl derivatives. A polymer was obtained from (9) but a dimer of perfluoro-2,4-di-isopropylazete (16) is obtained, from (15) quantitatively. The endo structure of the dimer is revealed by formation of a stable carbanion on addition of CsF. Trapping of the azete (16) with furan gave interconvertible 1 :1 cycloaddition products. Products consistent with co-dimerisation of azetes are described.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1990, 975-981

Photochemistry of halogenocarbon compounds. Part 5. Photolysis of fluorinated 1,2,3-triazine derivatives

R. D. Chambers, T. Shepherd and M. Tamura, J. Chem. Soc., Perkin Trans. 1, 1990, 975 DOI: 10.1039/P19900000975

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