Minimisation of sample matrix effects and signal enhancement for trace analytes using anodic stripping voltammetry with detection by inductively coupled plasma atomic emission spectrometry and inductively coupled plasma mass spectrometry

Abstract

An on-line flow system for anodic stripping voltammetry has been investigated for the pre-concentration of cadmium and copper and the separation of copper from a sodium matrix for detection by inductively coupled plasma atomic emission spectrometry and inductively coupled plasma mass spectrometry (ICP-MS). Good signal enhancement was obtained with pre-concentration of moderate sample volumes. Matrix elimination of more than 99% was possible for reasonably high concentrations of undesired matrix elements, namely Na and U. Isotope ratio data for ICP-MS indicated that the interference of ArNa⁺ on Cu⁺ at m/z 63 could be minimised.