The exchange reaction of C—D to C—H in the methyl group of methoxide species on an Sm2O3 catalyst under an H2 atmosphere has been observed by in situ infrared spectroscopy.
Y. Sakata, M. Yoshino, H. Imamura and S. Tsuchiya, J. Chem. Soc., Faraday Trans., 1990, 86, 3489 DOI: 10.1039/FT9908603489
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