The electrochemical reduction of thionine and methylene blue in the presence of Fe3+ has been examined in terms of a catalytic regenerative mechanism. The catalytic currents due to homogeneous chemical reaction between leucodyes and Fe3+ have been used to estimate rate constants.
A. S. N. Murthy and T. Srivastava, J. Chem. Soc., Faraday Trans., 1990, 86, 105 DOI: 10.1039/FT9908600105
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