Enthalpies of dilution in water of binary aqueous solutions of n-diols of increasing alkyl chain length are performed using a flow microcalorimeter. The pairwise enthalpic coefficients of these hydrophobic solutes depend mainly on the mutual positions of the —OH groups in the molecule. A rationalization of the excess enthalpies of positional isomers is attempted.
C. Cascella, G. Castronuovo, V. Elia, R. Sartorio and S. Wurzburger, J. Chem. Soc., Faraday Trans., 1990, 86, 85 DOI: 10.1039/FT9908600085
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