Issue 11, 1990
From the journal:

Journal of the Chemical Society, Dalton Transactions

Notes. Upon the fluxionality of [RhCl(PPh3)(Ph2PO2CCH[double bond, length as m-dash]CHMe)]

Derek J. Irvine,   Andrzej F. Borowski  and  David J. Cole-Hamilton  

Abstract

The fluxional behaviour of [RhCl(PPh3)(Ph2PO2CCH[double bond, length as m-dash]CHMe)] observed in the n.m.r. spectra is attributed to the rapid equilibrium between two isomers having mutually cis and trans phosphorus atoms respectively. Thermodynamic parameters for this process are measured and loss of P–P but not Rh–P coupling under fast exchange conditions suggests that Jpp has different signs for the two isomers

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Article information

DOI
https://doi.org/10.1039/DT9900003549
Article type
Paper

J. Chem. Soc., Dalton Trans., 1990, 3549-3550

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Notes. Upon the fluxionality of [RhCl(PPh3)(Ph2PO2CCH[double bond, length as m-dash]CHMe)]

D. J. Irvine, A. F. Borowski and D. J. Cole-Hamilton, J. Chem. Soc., Dalton Trans., 1990, 3549 DOI: 10.1039/DT9900003549

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