Issue 2, 1990
From the journal:

Journal of the Chemical Society, Dalton Transactions

Crystal and molecular structures of the antiferromagnetic linear chain halide-bridged complexes [CrX2(MeCN)2](X = Cl or Br)

Dost M. Halepoto,   Leslie F. Larkworthy,   David C. Povey,   B. Joly Tucker  and  Gallienus W. Smith  

Abstract

Single-crystal X-ray analysis has shown that the acetonitrile complex [CrBr2(MeCN)2] is a bromide-bridged linear polymer in which the metal atom is in distorted octahedral co-ordination, with metal–ligand bond distances Cr–N 2.066(4), Cr–Br, two at 2.545(0) and two at 2.976(1)Å. The Cr … Cr separation is 4.054(4)Å. The complexes [CrBr2(MeCN)2] and [CrCl2(MeCN)2] are isomorphous, and both are antiferromagnetic (J≈– 1.5 cm–1g= 2.0).

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Article information

DOI
https://doi.org/10.1039/DT9900000699
Article type
Paper

J. Chem. Soc., Dalton Trans., 1990, 699-701

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Crystal and molecular structures of the antiferromagnetic linear chain halide-bridged complexes [CrX2(MeCN)2](X = Cl or Br)

D. M. Halepoto, L. F. Larkworthy, D. C. Povey, B. J. Tucker and G. W. Smith, J. Chem. Soc., Dalton Trans., 1990, 699 DOI: 10.1039/DT9900000699

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