Issue 2, 1990
From the journal:

Journal of the Chemical Society, Dalton Transactions

Preparation and properties of [M{S2N3(SO2NH2)}(PR3)2] and [Pt{SO2(NH)2}(PR3)2] from reactions in liquid ammonia

Ivan P. Parkin  and  J. Derek Woollins  

Abstract

Reaction of SO2(NH2)2 or SO2Cl2 in liquid ammonia with [PtCl2(PR3)2] gives [Pt{SO2(NH)2}(PR3)2](PR3= PMe2Ph, PMePh2, PPh3, PEt3, or ½Ph2PCH2CH2PPh2) in good yield (ca. 70% isolated). Reaction of SOCl2 in liquid ammonia with [TiCl2(C5H5)2] or [PtCl2(PR3)2] yields [Ti(NSO)2(C5H5)2] and [Pt(NSO)2(PR3)2] respectively in ca. 60% yield. The compound S4N4O2 in liquid ammonia reacts with [MCl2(PR3)2] to produce [M{S2N3(SO2NH2)}(PR3)2](M = Pt, PR3= PMe2Ph, PMePh2, PEt3, PPrn3, or PBun3; M = Pd, PR3=½Ph2PCH2CH2PPh2) in fair yield (ca. 40%). The reactivity of Na2SO4, H2NSO3H, SO3·NMe3, S3N2(NSO2CF3), NaHNSO2C6H4Me, (NSOR)3, and H2NSO2Ph in liquid ammonia has also been investigated. The new compounds were characterised by 31P and 1H n.m.r., i.r., mass spectroscopy, and microanalyses.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/DT9900000519
Article type
Paper

J. Chem. Soc., Dalton Trans., 1990, 519-523

Permissions

Request permissions

Preparation and properties of [M{S2N3(SO2NH2)}(PR3)2] and [Pt{SO2(NH)2}(PR3)2] from reactions in liquid ammonia

I. P. Parkin and J. D. Woollins, J. Chem. Soc., Dalton Trans., 1990, 519 DOI: 10.1039/DT9900000519

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements